A new organotellurium compounds based on camphor, aniline and p-toluidine: preparation, characterization and theoretical study

The present study involved the preparation of organomercury and organotellurium compounds derived from camphor (2-amino-5-methylphenyl) mercury (II) chloride their derivatives by a condensation reaction. Characterization studied was carried out using infrared spectrum (IR), proton nuclear magnetic resonance (1H NMR), elemental analysis (C.H.N). molecular structure investigated density functional theory with hybrid (B3LYP) basis set 3-21G. Geometrical structure, HOMO surfaces, LUMO energy gap have been produced throughout geometry optimization. contours for were geometrical donor acceptor properties comparing highest occupied orbital energies (HOMO) compounds. electronegativity, electrophilicity, Ionization potential, electron affinity, Chemical Hardness, softness calculated molecules under study.